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Reactions of Phosphorus Compounds. IX. Synthesis of a Series of 2H-1-benzopyrans and Determination of the Mechanism of Reaction

✍ Scribed by Schweizer, Edward E.; Shaffer, E. T.; Hughes, C. T.; Berninger, C. J.

Book ID: 126212148
Publisher: American Chemical Society
Year: 1966
Tongue: English
Weight: 662 KB
Volume: 31
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo01347a040

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Reaction of 3,2, 6, benzopyran with either organolithium reagents or magnesium generates the novel strained alkyne, 3,4-didehydro-2H-[1]benzopyran. Cycloaddition with furans gives access to the dibenzo[b,d]pyran system.

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