Reactions of perfluoro-bicyclobutenyl and -bicyclopentenyl

✍ Scribed by R.D. Chambers; T. Nakamura

• Book ID: 104150492
• Publisher: Elsevier Science
• Year: 1991
• Tongue: English
• Weight: 30 KB
• Volume: 54
• Category: Article
• ISSN: 0022-1139
• DOI: 10.1016/s0022-1139(00)83765-3

✦ Synopsis

The novel dienes (1) and ( ) have been synthesised recently' and the highly strained system (1) shows extreme reactivity. For example, diene(1) reacts with fluoride-ion to give a dimer, which gives lgF-n.m.r. data consistant with structure (3), while diene (2) gives an observable anion (4) with caesium fluoride.

CsF CsF