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Reaction of perfluoro ketones with hexamethyldisilazane

✍ Scribed by L. A. Simonyan; É. A. Avetisyan; N. P. Gambaryan


Book ID
112423032
Publisher
Springer
Year
1972
Tongue
English
Weight
94 KB
Volume
21
Category
Article
ISSN
1573-9171

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On the reaction of P4S10 with hexamethyl
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P 4 S 10 reacts with (Me 3 Si) 2 NH, to give SP(NHSi-Me 3 ) x (SSiMe 3 ) 3‫מ‬x , where x ‫ס‬ 0-3. These species were shown by 31 P NMR spectroscopy to subsequently form cyclic and linear condensation products. The molecular structure of a linear trimer (Me 3 SiNH)P(S)[(l-NH)P(S)(NHSiMe 3 ) 2 ] 2 , 1