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Reactions of p-toluenesulfonates with lithium triethylborohydride. Visible and hidden rearrangements

✍ Scribed by Binkley, Roger W.


Book ID
127259330
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
528 KB
Volume
50
Category
Article
ISSN
0022-3263

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Competitive formation of cellulose p-tol
✍ Charles L. McCormick; Timothy R. Dawsey; J.Kent Newman πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 592 KB

The homogeneous preparation of a cellulose p-toluenesulfonate (tosylate) in N,N-dimethylaceta-mid+lithium chloride (DMAc-LiCl) is hampered by solvolysis of the p-toluenesulfonyl chloride (tosyl chloride). This Vilsmeier-Haack type reaction results in competitive formation of cellulosep-toluenesulfon