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Alkylation with Long Chain p-Toluenesulfonates. VI. Friedel—Crafts Reaction of n-Octadecyl p-Toluenesulfonate and Benzene 1

✍ Scribed by Shirley, David A.; Zietz, Joseph R.

Book ID: 127392284
Publisher: American Chemical Society
Year: 1953
Tongue: English
Weight: 296 KB
Volume: 75
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja01120a532

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The rate data for the Menschutkin reaction between strongly activated Z-substituted benzyl ptoluenesulfonates and Y-substituted N,N-dimethylanilines in acetonitrile at 35 °C fit the equation, , which is consistent with concurrent first-and second-order processes. The k 1 and k 2 values for each sub