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Reactions of ortho-Aminophenols and ortho-Aminothiophenols with 1,3,5-Trinitrobenzene.

โœ Scribed by Mikhail D. Dutov; Sergei S. Vorob'ev; Ol'ga V. Serushkina; Svyatoslav A. Shevelev; Bogdan I. Ugrak; Vadim V. Kachala

Publisher
John Wiley and Sons
Year
2007
Weight
22 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

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Reaction of 1,8-Diazabicyclo(5.4.0)undec-8-ene with Methyl 3,5-Dinitrobenzoate and 1,3,5-Trinitrobenzene. -The initial reaction of DBU (II) with title compounds (I) and (V) gives the corresponding Meisenheimer complexes which undergo oxidation and ipso-displacement to form crimson 2-aminoindole der