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Reactions of organic anions : XLIV. Catalytic synthesis of phenyl(trihalomethyl)mercury compounds in aqueous medium

✍ Scribed by M. Fedoryński; M. Makosza

Book ID
108354292
Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
271 KB
Volume
51
Category
Article
ISSN
0022-328X

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Reactions of organic anions. XLIII. Catalytic method for synthesis of glycidic nitriles in aqueous medium
✍ A. Jończyk; M. Fedoryński; M. Ma̧kosza 📂 Article 📅 1972 🏛 Elsevier Science 🌐 French ⚖ 131 KB

Darzens condensation between d-halocarbanions and carbonyl compounds that leads to the formation of glycidic acid derivatives is useful tool in synthesis. Generally the d-halocarbanions are generated by action of dry sodium alkoxides, amide, hydride or other such agents on cc-haloesters, nitriles,