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Reactions of nitroimidazoles. Nucleophilic substitution of the nitro group

โœ Scribed by Goldman, P.; Wuest, James D.

Book ID
111945251
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
393 KB
Volume
103
Category
Article
ISSN
0002-7863

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Radical-nucleophilic substitution (SRN1)
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โœ Suleiman I. Al-Khalil; W.Russell Bowman ๐Ÿ“‚ Article ๐Ÿ“… 1983 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 257 KB

cL-Nitro-thiocyanates undergo substitution by a SRNI mechanism with a range of anions to give Loss of thiocyanate, corroborating behaviour observed for the intermediate a-nitrothiocyanato radical-anions by e.s.r. spectroscopy.