Radical-nucleophilic substitution (SRN1) reactions of α-nitro-thiocyanates
✍ Scribed by Suleiman I. Al-Khalil; W.Russell Bowman
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 257 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
cL-Nitro-thiocyanates undergo substitution by a SRNI mechanism with a range of anions to give Loss of thiocyanate, corroborating behaviour observed for the intermediate a-nitrothiocyanato radical-anions by e.s.r. spectroscopy.
📜 SIMILAR VOLUMES
Regioselective replacement of nitro group in cyclic c-(nitroalkyl)enones by various nucleophiles such as stabilized carbanions, amine, NaN3, PhSO2Na and PhSNa provides the overall SN2 type products.
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