Reactions of nitric oxide coordinated to metals
โ Scribed by Jon A. McCleverty
- Publisher
- Elsevier Science
- Year
- 1981
- Weight
- 235 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0304-5102
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๐ SIMILAR VOLUMES
The recombination of radicals in premixed frames is investigated. The results for k2 and & are compared with those of Bulewicz and Sugden.
Rate constants for the reactions of 1 -and 2-hydroxyethyl radicals with O2 and NO were measured at room temperature by laser flash photolysis-photoionization mass spectrometry method. The results are as follows (in units of cm3 moleculec' s-I): CH>CHOH+O> ((2.8+0.2)x10-I'); CH,CHOH+NO ((2.4kO.6)XlWI
Amides were allowed to react with nitric oxide in aprotic and non-ethereal solvents to give the corresponding N-nittoso derivatives. The reaction was accelerated by addition of oxygen. The solvent effect revealed that the reaction did not proceed in the presence of protic media.