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Reactions of nitric oxide and nitrogen dioxide with functionalised alkenes and dienes †

✍ Scribed by Park, Jonathan S. B.; Walton, John C.


Book ID
118734483
Publisher
Royal Society of Chemistry
Year
1997
Tongue
English
Weight
103 KB
Volume
12
Category
Article
ISSN
1472-779X

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The reaction of methoxy radicals with ni
✍ L. Batt; G. N. Rattray 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 550 KB

By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio