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Reaction of hydrogen peroxide with nitrogen dioxide and nitric oxide

✍ Scribed by Gray, David; Lissi, Eduardo; Heicklen, Julian

Book ID: 121233277
Publisher: American Chemical Society
Year: 1972
Tongue: English
Weight: 652 KB
Volume: 76
Category: Article
ISSN: 0022-3654
DOI: 10.1021/j100658a001

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By allowing dimethyl peroxide ( 10-4M) to decompose in the presence of nitric oxide (4.5 X lOW5M), nitrogen dioxide (6.5 X 10-5M) and carbon tetrafluoride (500 Torr), it has been shown that the ratio kzlkz, = 2.03 f 0.47: CH30 + NO -CH30NO (reaction 2) and CH30 + NO2 -CH30N02 (reaction 2'). Deviatio