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Reactions of Nitrate Esters. III. Evidence for Nitrogen-Oxygen Cleavage in Reductions with Hydrazine and Alkaline Hydrosulfides

✍ Scribed by Merrow, Raymond T.; Van Dolah, Robert W.

Book ID
126495959
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
294 KB
Volume
77
Category
Article
ISSN
0002-7863

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Peroxynitrite (ONOO-) has been found to react with the title amine 1 and quinone 5 to form N-nitrosoamine 2 and 2,3-epoxide 6, respectively, in accord with the in situ generation of the nitrosonium and hydroperoxide ions as the respective reactive species.