✦ LIBER ✦

Reactions of peroxynitrite with N,N-dimethyl-p-toluidine and 1,4-naphthoquinone. Evidence for heterolytic cleavage of a nitrogenoxygen bond in peroxynitrous acid

✍ Scribed by Nobuaki Nonoyama; Kaori Hisatome; Chizuru Shoda; Hitomi Suzuki

Book ID: 104262022
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 129 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01239-3

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✦ Synopsis

Peroxynitrite (ONOO-) has been found to react with the title amine 1 and quinone 5 to form N-nitrosoamine 2 and 2,3-epoxide 6, respectively, in accord with the in situ generation of the nitrosonium and hydroperoxide ions as the respective reactive species.