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Reactions of N-substituted iminotriphenylphosphoranes and S4N4-Evidence for facile C-N'bond cleavage

✍ Scribed by T. Mohan; P. Senthivel; M. N. Sudheendra Rao


Book ID
112934894
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
1994
Tongue
English
Weight
36 KB
Volume
106
Category
Article
ISSN
0253-4134

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Peroxynitrite (ONOO-) has been found to react with the title amine 1 and quinone 5 to form N-nitrosoamine 2 and 2,3-epoxide 6, respectively, in accord with the in situ generation of the nitrosonium and hydroperoxide ions as the respective reactive species.