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Reactions of monothiooxamides with N-nucleophiles. Synthesis of 4,5-dihydroimidazole-2-carboxanilides

โœ Scribed by V. N. Yarovenko; S. A. Kosarev; I. V. Zavarzin; M. M. Krayushkin

Book ID
105596447
Publisher
Springer
Year
1999
Tongue
English
Weight
359 KB
Volume
48
Category
Article
ISSN
1573-9171

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Whereas I-benryl-2-lithtomethyl-4,5-dihydrotmidazole undergoes reverstble 1,2-addttton to aldehydes and ketones. the derived phosphonate salt, I-benzyl-2.lithio(diethylphosphono)methyl-4,5dihydroimidazole, affords the condensation products, 2.( 1 -alkenyl)-4,5-dihydroimidazoles; these latter undergo