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Reactions of monomeric cobalt-oxygen complexes. I. Thermodynamics of reaction of molecular oxygen with five- and six-coordinate amine complexes of a cobalt porphyrin

โœ Scribed by Walker, F. Ann.


Book ID
127388470
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
753 KB
Volume
95
Category
Article
ISSN
0002-7863

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The influence of pH and ligand structure on the reaction of cobalt(II) complexes with various dipeptides and molecular oxygen was examined. The minimum pH value required for the formation of dioxygen adducts was found to be about 6.5. This value should be related to amidic deprotonation of dipeptide