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A new approach to the study of the oxygenation reactions of transition-metal complexes. Formation of the .mu.-superoxo cobalt(III) complexes in the oxygenation reactions of cobalt(II) amines

โœ Scribed by Dhanasekaran, T.; Natarajan, P.


Book ID
126951074
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
398 KB
Volume
114
Category
Article
ISSN
0002-7863

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The influence of pH and ligand structure on the reaction of cobalt(II) complexes with various dipeptides and molecular oxygen was examined. The minimum pH value required for the formation of dioxygen adducts was found to be about 6.5. This value should be related to amidic deprotonation of dipeptide