On Reactions of Oxygenated Cobalt(II) Complexes. XI. Note on the Mechanism of O2 Uptake by Cobalt(II) Chelates with Tetra- and Pentadentate Amines

Effect of solvent on the reactions of co

Effect of solvent on the reactions of coordination complexes: Part 16. Kinetics and mechanism of complexation of oxalatopentaammine-cobalt(III) with nickel(II) in methanol-water medium

✍ Anadi C. Dash; Jyotshamayee Pradhan 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 468 KB 👁 1 views

## Abstract The kinetics of reversible complexation of oxalatopentaammine cobalt(III) with Ni^2+^ has been investigated in MeOH + water media (0–50 (v/v) % MeOH) at 15.0–35.0°C and I = 0.10 mol dm^−3^. Analysis of rate data indicates that the monobonded complex [(NH~3~)~5~ · CoOCOCO~2~Ni]^3+^ in wh