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Reactions of Methylenecyclopropanes with Phenylsulfenyl Chloride and Phenylselenyl Chloride

✍ Scribed by Liu, Le-Ping; Shi, Min

Book ID
125942968
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
78 KB
Volume
69
Category
Article
ISSN
0022-3263

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We have reported that the reaction of methylsulfenyl halides with ad~antylideneadamantane (1) leads to the formation of a thiiranium salt (x), which in some instances can be isolated.' On treatment with nucleophiles the salt (2a) can undergo either desulfurization or -d~ethylation. ## CR3 x0 Virt