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Reactions of Methylenecyclopropanes with Phenylsulfenyl Chloride and Phenylselenyl Chloride.

✍ Scribed by Le-Ping Liu; Min Shi


Publisher
John Wiley and Sons
Year
2004
Weight
111 KB
Volume
35
Category
Article
ISSN
0931-7597

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We have reported that the reaction of methylsulfenyl halides with ad~antylideneadamantane (1) leads to the formation of a thiiranium salt (x), which in some instances can be isolated.' On treatment with nucleophiles the salt (2a) can undergo either desulfurization or -d~ethylation. ## CR3 x0 Virt