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Reactions of manganese, rhodium, and iron allyl complexes with organometallic nucleophiles

✍ Scribed by O. V. Gusev; V. V. Krivykh; M. I. Rybinskaya

Book ID
112447046
Publisher
Springer
Year
1987
Tongue
English
Weight
361 KB
Volume
36
Category
Article
ISSN
1573-9171

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Reaction of tetracarbonyl(Ο€-allyl)mangan
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✍ William S. Vaughan; Henry H. Gu; Keith F. McDaniel πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 192 KB

## Nucleophilic attack an tetracarbonyl(~aUyl)manganese takes place at the terminus of the ~.system, generating aUylated products in 44-95% yield after oxidation. Stabilized nucleophiles (pKa 12-20) give mainly his aUylation whereas nonstabilized nucleophiles (pKa [25][26][27][28][29][30][31][32][