Reaction of tetracarbonyl(π-allyl)manganese with carbon nucleophiles

✍ Scribed by William S. Vaughan; Henry H. Gu; Keith F. McDaniel

• Book ID: 104256598
• Publisher: Elsevier Science
• Year: 1997
• Tongue: French
• Weight: 192 KB
• Volume: 38
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(97)00227-x

✦ Synopsis

Nucleophilic attack an tetracarbonyl(~aUyl)manganese takes place at the terminus of the ~.system, generating aUylated products in 44-95% yield after oxidation. Stabilized nucleophiles (pKa 12-20) give mainly his aUylation whereas nonstabilized nucleophiles (pKa

[25][26][27][28][29][30][31][32][33][34][35]

give mono aUylation.