Reactions of lumiflavin and lumiflavin radicals with .cntdot.CO2- and alcohol radicals
✍ Scribed by Ahmad, Rizwan; Wu, Zhennan; Armstrong, D. A.
- Book ID
- 126225839
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 566 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0006-2960
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## Abstract The Hg(6^3^__P__~1~) photosensitized decompositions of 3‐methyl‐1‐butene, 2‐methyl‐2‐butene, 3,3‐dimethyl‐1‐butene, and 2,3‐dimethyl‐1‐butene have been used to generate 1‐methylallyl, 1,2‐dimethylallyl, 1,1‐dimethylallyl, and 1,1,2‐trimethylallyl radicals in the gas phase at 24 ± 1°C. F
CzH50NO was photolyzed with 366 nm radiation at -48, -22, -2.5, 23, 55, 88, and 120°C in a static system in the presence of NO, 0,, and N,. The quantum yield of CH3CH0, (D{CH3CHO), was measured as a function of reaction conditions. The primary photochemical act is (la) CZHSONO + hv -\* CzH50 + NO an