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Reactions of lithium dimethylamide with some borane derivatives. Evidence for the displacement of lithium hydride

✍ Scribed by Keller, Philip C.


Book ID
126079067
Publisher
American Chemical Society
Year
1975
Tongue
English
Weight
458 KB
Volume
14
Category
Article
ISSN
0020-1669

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Addition compounds of alkali metal hydri
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Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T