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Mechanism of Reaction of Geminal Dihalides with Lithium Aluminum Hydride. Evidence for Single Electron Transfer as the Major Reaction Pathway

โœ Scribed by Ashby, E. C.; Deshpande, Abhay K.


Book ID
118270952
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
1017 KB
Volume
59
Category
Article
ISSN
0022-3263

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Evidence for a single electron transfer
โœ E.C. Ashby; R.N. DePriest; A. Tuncay; Sushil Srivastava ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 210 KB

It has been demonstrated by means of spectroscopic studies involving cyclizable alkyl halides that lithium dimethylcuprate can react with organic halides by a single electron transfer pathway. The reaction of lithium diorganocuprates (LiCuR2) with alkyl halides is of major synthetic imp0rtance.l