Reactions of LiNC(CF3)2 with halides
✍ Scribed by Richard F. Swindell; Thomas J. Ouellette; Daniel P. Babb; Jean'ne M. Shreeve
- Book ID
- 107768594
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 106 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0020-1650
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The new compounds, CF3SF(0)=NCF3 and CF3SF(=NCH3)=NCF3, result from nucleophilic displacement reactions of CF3SF3=NCF3 with water and methylamine, respectively. Higher yields of the di-imine are obtained when CH3N(Si(CH3)3)2 is substituted for CH3NH2. Stable fluoroamines, CF3SF4N(F)Rf (Rf = CF3, C2F
The hydrogen transfer reaction between C2H6 and CFs radicals, generated by the photolysis of CF31, has been studied in the temperature range 298-617 K. The rate constant, based on the value of 1013 36 cm3 mo1-l s-' for the recombination of CFs radicals, is given by log kp = (11.90 2 0.09) -(33230 \_