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Reactions of isoprenoids. XIII. 1,4-Cycloaddition reactions of alloocimene with various dienophiles

✍ Scribed by Sasaki, Tadashi; Eguchi, Shoji; Yamada, Hiroto


Book ID
127007063
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
687 KB
Volume
36
Category
Article
ISSN
0022-3263

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Cycloaddition reactions of heteroazadien
✍ JosΓ© Barluenga; Miguel TomΓ‘s; Alfredo Ballesteros; Luis A. LΓ³pez πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 209 KB

Summmy. 1-Thia-3-azabutadienes cleanly undergo [4 + 21 cycloaddition processes with electron-poor dienophiles; the reaction is regioselective and leads exclusively to the endo isomer.