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Cycloaddition reactions of heteroazadienes: [4+2] cycloaddition of 1-thia-3-azabutadienes with electron-poor dienophiles

✍ Scribed by José Barluenga; Miguel Tomás; Alfredo Ballesteros; Luis A. López

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 209 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93390-8

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✦ Synopsis

Summmy. 1-Thia-3-azabutadienes cleanly undergo [4 + 21 cycloaddition processes with electron-poor dienophiles; the reaction is regioselective and leads exclusively to the endo isomer.

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