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Reactions of isolated organic ions. Alkene loss from the immonium ions CH3CH?N+HC2H5 and CH3CH?N+HC3H7

โœ Scribed by Bowen, Richard D.


Book ID
120048588
Publisher
Royal Society of Chemistry
Year
1989
Tongue
English
Weight
734 KB
Volume
7
Category
Article
ISSN
1472-779X

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Unimolecular reactions of the isolated i
โœ Richard D. Bowen; Alex. W. Colburn; Peter J. Derrick ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 858 KB

The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms