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Reactions of iron-η1-allyl complexes with mercury (II) chloride

✍ Scribed by L.J. Dizikes; A. Wojcicki

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
138 KB
Volume
20
Category
Article
ISSN
0020-1693

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✍ Keith F. McDaniel; Larry R. Kracker II; Parinbam K. Thamburaj 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 271 KB

Reaction of organolithium reagents with &xuuadienyl iron complex 4 occurs at the WC4 position of the x-system generating s+-iron complexes 5. Air oxidation of these a,+-iron complexes generates cyclohexenones. Reaction of the slightly more electron-poor r$pentadienyl iron complex 11 gives nucleophil