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Iron(III) Chloride Catalyzed Effective Allylation Reactions of Aldehydes with Allyltrimethylsilane.

✍ Scribed by Tsutomu Watahiki; Takeshi Oriyama


Publisher
John Wiley and Sons
Year
2003
Weight
165 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract The direct substitution of alcohols and β‐dicarbonyl compounds was catalyzed with FeCl~3~ under solvent‐free conditions. The catalyst loading could be decreased to 0.01 mol% at high activities. It was shown that the reaction proceeded in two steps via the etherification of the alcohols.