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Reactions of indole sulfoxides with dichloroketene: a new approach to the physostigmine alkaloids

✍ Scribed by Marino, Joseph P.; Kim, Min Woo; Lawrence, Ross


Book ID
127287880
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
400 KB
Volume
54
Category
Article
ISSN
0022-3263

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As part of our continuing study of the use of N-aryl nitrones in ortho-selective aromatic substitution reactions l-3 , we have investigated the reaction of a number of such nitrones with dichloroketene. These reactions lead to adducts which can be hydrolysed by boiling water or aqueous acid to isati