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Reactions of hydrogen peroxide with metal complexes. 9. Kinetic studies on the reaction of hydrogen peroxide with (5,10,15,20-tetrakis(4-N-methylpyridiniumyl)porphine(2+))oxotitanium(IV) in aqueous solutions. Evidence for an associative-interchange mechanism

✍ Scribed by Inamo, Masahiko; Funahashi, Shigenobu; Tanaka, Motoharu


Book ID
115516137
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
640 KB
Volume
24
Category
Article
ISSN
0020-1669

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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o