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Kinetic studies on the peroxo complex formation of oxo(5,10,15,20-tetra-4-pyridylporphinato)titanium(IV) with hydrogen peroxide. Evidence for an associative mechanism

โœ Scribed by Masahiko Inamo; Shigenobu Funahashi; Motoharu Tanaka


Book ID
108323861
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
163 KB
Volume
76
Category
Article
ISSN
0020-1693

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โœ Tapan Kumar Saha; Subarna Karmaker; Keietsu Tamagake ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 279 KB ๐Ÿ‘ 3 views

High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o