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Reactions of hydrogen peroxide with metal complexes. 6. Kinetic studies of the reactions of hydrogen peroxide with aqua(nitrilotriacetato)oxovanadate(IV) and diaquaoxo(2,6-pyridinedicarboxylato)vanadium(IV) in acidic aqueous solution

โœ Scribed by Funahashi, Shigenobu.; Funada, Setsuko.; Inamo, Masahiko.; Kurita, Reeko.; Tanaka, Motoharu.


Book ID
127309232
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
527 KB
Volume
21
Category
Article
ISSN
0020-1669

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High-valent oxo-iron(IV) species are commonly proposed as the key intermediates in the catalytic mechanisms of iron enzymes. Water-soluble iron(III) tetrakis-5,10,15,20-(N-methyl-4-pyridyl)porphyrin (Fe(III)TMPyP) has been used as a model of heme-enzyme to catalyse the hydrogen peroxide (H 2 O 2 ) o