## Γczyk on the occasion of his 60th birthday The reactions of sterically crowded cycloalkanethiones of type 2 with CHCl 3 /NaOH under phase-transfer catalysis (PTC) with benzyl(triethyl)ammonium chloride (TEBA) as catalyst afforded the corresponding gem.dichlorothiiranes of type 3 in good yields
Reactions of Hexachlorodisilane with Methylene and Dichlorocarbene
β Scribed by Priv.-Doz. Dr. Manfred Weidenbruch; Dipl.-Chem. Claude Pierrard
- Publisher
- John Wiley and Sons
- Year
- 1973
- Tongue
- English
- Weight
- 233 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
β¦ Synopsis
angles between Te atoms are similar to those in elemental tellurium. The shortest atom separations between neighboring building units are 3.4 A.
Structure analyses for the isotypic halides Te,X were carried out with Te,Br and TeJ. 748 reflections for the bromide (6,,,=25") and 1255 reflections for the iodide
π SIMILAR VOLUMES
I - (2,4,-l -phosphaallene reacted with dichlorocarbene to give 2-dichloromethylene-l-(2,4,6-tri-t-butylphenyl)-l -phosphirane. The structure was confirmed by X-ray crystal structure analysis. A similar isomerization product was obtained in the reaction of dichlorocarbene with 3-phenyl-l-(2,4,6-trit