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Reactions of group Vb chlorides with boron trichloride and gallium trichloride

โœ Scribed by R.R. Holmes

Book ID
118904113
Publisher
Elsevier Science
Year
1960
Weight
314 KB
Volume
14
Category
Article
ISSN
0022-1902

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## Abstract For Abstract see ChemInform Abstract in Full Text.

A glycosylation reaction: Conversion of
A glycosylation reaction: Conversion of methyl glycosides to glycosyl chlorides by boron trichloride.
โœ G.R. Perdomo; J.J. Krepinsky ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 25 KB

In the last paragraph on page 5596, the fifth line should read as follows: II . ..2.3.4-tri-o-beneyl mannopyranoside 16, 15X;..." In the schematic representation on page 5597, the substituents for compound 7 should be listed as follows: "Rl=NCS; R2=R5=Bn; R4=H."

A glycosylation reaction: Conversion of
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Methyl glycosides react readily with boron trichloride in dichloromethane solutions at -78 "C to give the corresponding glycosyl chlorides for subsequent use in glycosylation reactions. This reaction is compatible with the presence of glycosyl linkages in the molecule, as well as benzyl and acetyl