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Reactions of group IV organometallic compounds. XVI1 reactions of benzoyl heterocumulens with trimethylstannylalkylamines

✍ Scribed by Kenji Itoh; Isamu Matsuda; Yoshio Ishii


Publisher
Elsevier Science
Year
1969
Tongue
French
Weight
130 KB
Volume
10
Category
Article
ISSN
0040-4039

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✦ Synopsis


Benzoyl isocyanate and isothiocyanate were previously reported to be novel 2 acceptors for organosilylamines .

In this publication, reactions of benzoyl isocyanate, isothiocyanate, and t-butylcarbodiimide with trimethylstannylamines are presented.


πŸ“œ SIMILAR VOLUMES


Reaction of group IV organometallic comp
✍ Kenji Itoh; Yutaka Fukumoto; Yoshio Ishii πŸ“‚ Article πŸ“… 1968 πŸ› Elsevier Science 🌐 French βš– 165 KB

In the preceeding publicationl, reaction of N-methy~hex~le#yldistanna~ane (I) with carhrln disulfide or phenyl isothiocyanate was found to give bis(tri-met~yltin)su~fide(~I) and methyl isothiocyanate or methyl phenyl carbodiimide,

Reactions of group IV organometallic com
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Even though the addition reactions of N-alkylhexamethyldisilazane (Me3Si)SN-Me, with phenyl isocyenate haa been well established'--j, there was no ## * Identified with the authentic sample prepared from trimethylstznn;-1 6 chloride and sodium sulfide . \*\* Identified with the authentic s:nple8.

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