Reactions of group IV organometallic compounds. XVI1 reactions of benzoyl heterocumulens with trimethylstannylalkylamines
β Scribed by Kenji Itoh; Isamu Matsuda; Yoshio Ishii
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 130 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Benzoyl isocyanate and isothiocyanate were previously reported to be novel 2 acceptors for organosilylamines .
In this publication, reactions of benzoyl isocyanate, isothiocyanate, and t-butylcarbodiimide with trimethylstannylamines are presented.
π SIMILAR VOLUMES
In the preceeding publicationl, reaction of N-methy~hex~le#yldistanna~ane (I) with carhrln disulfide or phenyl isothiocyanate was found to give bis(tri-met~yltin)su~fide(~I) and methyl isothiocyanate or methyl phenyl carbodiimide,
Even though the addition reactions of N-alkylhexamethyldisilazane (Me3Si)SN-Me, with phenyl isocyenate haa been well established'--j, there was no ## * Identified with the authentic sample prepared from trimethylstznn;-1 6 chloride and sodium sulfide . \*\* Identified with the authentic s:nple8.
## Reactions of CF3CF2CF=CC12 ( ) 1 with various nucleophiles such as MeO-, PhO-, NH3, n-C4HgMgBr and n-C4HgS-were studied. Contrary to a prior report [31, the addition is bidirectional and except for PhO-, nucleophiles would rather attack the CF= site (path 1) than the =CC12 site (path 2), no mat