Reactions of 1-Alkynylphosphonates with Group (IV) Complexes
β Scribed by Abed Al-Aziz Al-Quntar; Morris Srebnik
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Arrhenius parameters have been measured for the abstraction of hydrogen from the C Si, Ge, and Sn tetramethyls: The rate constants correlate with the proton chemical shift, which is related to a polar effect. In all cases except carbon, a hotβmolecule Ξ²βfluorine rearrangementβeliminat