Nestive ions zue shown to lad to so!vated ions in 'he \_ms phzsse by rcsction with estew of formic acid w&n two requirements ar"-mat: (1) the bond energy of the cluster is grezter than 9.3 kczljmole, and (2) the proton nfimity of the negative ion is gcater tisn 3:9 kcaliniole. A likely mechanism for
Reactions of formic acid with protonated water clusters: Implications of cluster growth in the atmosphere
β Scribed by Goken, E. G.; Castleman, A. W.
- Book ID
- 119677396
- Publisher
- American Geophysical Union
- Year
- 2010
- Tongue
- English
- Weight
- 513 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0148-0227
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Reaction cross sections for the reactions of protonated water clusters, H ΓΎ (H 2 O) n (n ΒΌ 1-6) with dimethylsulfoxide (DMSO) were measured at the collision energy of 0.1 eV. The cross section at n ΒΌ 2, which was found to be twice as large as that at n ΒΌ 4, showed a possibility of direct proton tran
## Abstract __The effect of a single water molecule on the reaction mechanism of the gasβphase reaction between formic acid and the hydroxyl radical was investigated with highβlevel quantum mechanical calculations using DFTβB3LYP, MP2 and CCSD(T) theoretical approaches in concert with the 6β311+G(2