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Energy requirements for the indirect formation of cluster ions in the gas phase: the ion-molecule reaction of negative ions with esters of formic acid

✍ Scribed by Paulo Celso Isolani; José Manuel Riveros

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
261 KB
Volume
33
Category
Article
ISSN
0009-2614

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✦ Synopsis

Nestive ions zue shown to lad to so!vated ions in 'he _ms phzsse by rcsction with estew of formic acid w&n two requirements ar"-mat: (1) the bond energy of the cluster is grezter than 9.3 kczljmole, and (2) the proton nfimity of the negative ion is gcater tisn 3:9 kcaliniole. A likely mechanism for due bimolecular process is suggested based on these results.

Several recent papers from our laboratory have discussed bimolecular ion--neutral reactions which result in the indirect formation of gas phase solvated negative ions at pressures of 10-" torr [I+] . While a quantita-

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