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Reactions of fluoro olefins Communication 9. Action of anhydrous aluminum chloride on fluoro olefins

โœ Scribed by R. N. Sterlin; V. A. Sidorov; I. L. Knunyants


Book ID
112435893
Publisher
Springer
Year
1959
Tongue
English
Weight
195 KB
Volume
8
Category
Article
ISSN
1573-9171

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Reaction of bistrifluoromethylaminosulph
โœ Colin F. Service; Anthony E. Tipping ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 209 KB

Reaction of bistrifluoromethylaminosulphenyl chloride with unsymmetrical fluoro-olefins in daylight or under photochemical conditions gives both possible I:1 adducts (ca. I:1 ratio) arising from homolytic fission of the S-Cl bond. Addition to octafluorobut-2-ene and hexafluorobut-2-yne gives mixture