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One-step synthesis of trialkylaluminum derivatives and dialkylaluminum hydrides by the reaction of alkaline metal aluminum hydrides with α-olefins and alkylaluminum chlorides

✍ Scribed by V. V. Gavrilenko

Book ID
110419638
Publisher
Springer
Year
2003
Tongue
English
Weight
195 KB
Volume
52
Category
Article
ISSN
1573-9171

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Addition compounds of alkali metal hydri
Addition compounds of alkali metal hydrides—XIX: Rapid reaction of trialkylboranes with lithium aluminum hydride in the presence of triethylene-diamine. A facile and quantitative synthesis of lithium trialkylborohydrides, including derivatives with exceptionally large steric requirements
✍ Herbert C. Brown; John L. Hubbard; Bakthan Singaram 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 403 KB

Abdrad-Trialkylborancs react rapidly with lithium aluminium hydride (LAH) in dicthyl ether in the presence of triethykncdiamim (TED) at 0" to form the corresponding lithium triakylborohydrides and aluminum hydride. The aluminum hydride precipitates out of solution as its triethylenediamine adduct. T