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Reactions of fluorine atoms with iodides studied by crossed beam laser-induced fluorescence

โœ Scribed by Yuanwu Qiu; Shikang Zhou; Songhao Liu


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
435 KB
Volume
136
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The reactions of F atoms with C2HSI, C2FSI, and n-CjHSI were studied by the crossed beam laser-induced fluorescence techniques within the 570-620 nm wavelength region. The vibrational and rotational excitation spectra of the reaction product IF were measured. The relative vibrational population densities of v= 3,4, and 5 vibrational levels, and some of the relative detailed vibrational rate constants, the rotational temperatures, and the mean fractions of rotational energy in individual vibrational states of the reaction product IF were obtained. The reaction mechanism was discussed.


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