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Reactions of dithioxo-1,3,2λ5,4λ5-dithiadiphosphetanes with triorganolead derivatives

✍ Scribed by Il'yas S. Nizamov; Vladislav A. Kuznetzov; Elvira S. Batyeva

Publisher: John Wiley and Sons
Year: 1997
Tongue: English
Weight: 144 KB
Volume: 8
Category: Article
ISSN: 1042-7163
DOI: 10.1002/(sici)1098-1071(1997)8:4<323::aid-hc6>3.0.co;2-b

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✦ Synopsis

The reactions of Lawesson's reagent 1a and its 4-ethoxy homologue 1b with triethyl-and triphenyl(alkoxy)plumbanes 2a,b and -(alkylthio)plumbanes 4a,b were studied. On the basis of these reactions, novel, advantageous methods of synthesizing S-triethyl and triphenylplumbyl derivatives of aryldithio-and trithiophosphonic acids 3a-d and 5a,b were developed. ᭧

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