Reactions of distabilized β-dicarbonyl sulfonium and iodonium ylides with isocyanates
✍ Scribed by Yu. G. Gololobov; I. R. Golding; M. A. Galkina; B. V. Lokshin; I. A. Garbuzova; P. V. Petrovskii; Z. A. Starikova; B. B. Averkiev
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 527 KB
- Volume
- 55
- Category
- Article
- ISSN
- 1573-9171
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
Transition metal-catalyzed decomposition of phenyliodonium and diphenylsulfonium ylides was investigated with regard to application in asymmetric carbenoid reactions. Phenyliodonium ylides react in the presence of Rh(II) catalysts with the same selectivity in inter-and intramolecular cyclopropanatio
## Abstract An efficient and mild reaction for introducing an allylic moiety and an alkylthio‐ or alkylseleno‐group onto the α‐carbon of β‐dicarbonyl compounds in one step by tandem transylidation and [2,3]‐sigmatropic rearrangement is described.