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Reactions of Dimethyl Carbonate with Aliphatic Amines Under High Pressure

✍ Scribed by Margetić, Davor; Antonac, Irena Zrinski; Glasovac, Zoran; Eckert-Maksić, Mirjana; Maksimović, Ljiljana

Book ID
126565647
Publisher
Taylor and Francis Group
Year
2011
Tongue
English
Weight
297 KB
Volume
41
Category
Article
ISSN
0039-7911

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The syntheses of carbamates from reactio
The syntheses of carbamates from reactions of primary and secondary aliphatic amines with dimethyl carbonate in ionic liquids
✍ Tianlong Sima; Shu Guo; Feng Shi; Youquan Deng 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 91 KB

At 170°C and using ionic liquids as solvent and catalyst, primary and secondary aliphatic amines could react with dimethyl carbonate to give alkyl carbamates with good yield. Due to its insolubility, the desired carbamate solid could be recovered by simple filtration from the two-layer mixture of di