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Reactions of difluorocarbene with conjugated polyfluorodienes

โœ Scribed by V. A. Petrov; S. D. Chepik; G. G. Belen'kii; L. S. German

Book ID
112449498
Publisher
Springer
Year
1990
Tongue
English
Weight
100 KB
Volume
39
Category
Article
ISSN
1573-9171

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Difluomoarbene reaote with 1.2.2-trimethylbioyaloU.l.Dlbutane to give the product of two bond aleavage. 1.1~difhmro-3,3,4-trimethyl-1, I-pentadiene in 3% yidli. Bicyclo[2.l.Olpentane ia even leee reeative. yielding l,l-difluorohexa-1,5diene in 08. 0.5% yield. Bioyolo[3.l.Olhexane does not reaot with