New pathway for the reaction of difluorocarbene with imines
β Scribed by McCarthy, James R.; Barney, Charlotte L.; O'Donnell, Martin J.; Huffman, John C.
- Book ID
- 121484193
- Publisher
- The Royal Society of Chemistry
- Year
- 1987
- Tongue
- English
- Weight
- 203 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0022-4936
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## Abstract The addition of difluorocarbene to bicyclo[2.2.2]octaβ2,5βdiene gave the __exo__ and __endo__ 1:1 cyclopropane adducts. In contrast to norbornadiene, no __homo__β1,4 adduct was formed. The adducts were thermally stable under the conditions of their formation and separation (<170Β°). Howe
Steric and mesomeric effects have a marked influence upon the formation of oxaziridine (normal pathway) or nitrone (abnormal pathway) products from the imine-peroxyacid reaction; n.m.r. studies of the thermal isomerization of oxaziridines to nitrones provide evidence of a pseudo-abnormal oxidation p